康熙青花色料的仿制研究

发布时间：2018-01-14 04:28

本文关键词：康熙青花色料的仿制研究　出处：《中国陶瓷》2015年03期 　论文类型：期刊论文

【摘要】：以探索再现研制康熙青花色料为目的,在Co-Al尖晶石为基础的钴蓝色料中引入不同比例的Fe2O3和MnO2,并探讨其对合成康熙青花色料的呈色影响。通过XRD、能谱仪及色度仪对样品进行测试分析,研究表明,随着Fe/Co值的升高,青花色料的呈色逐渐由明蓝向暗蓝色转变;Mn/Co值的升高,青花色料的呈色逐渐由明蓝色向灰青色转变。在合成过程中得到不同比例的CoAl2O4、FeAl2O4、MnAl2O4、Mn0.83Al1.96Fe0.21O4晶体,这些物质与游离态的铁、钴、锰离子所形成的化合物共同作用,影响着青花色料的呈色效果。
[Abstract]:For the purpose of exploring and developing Kangxi blue and blue pigment, different proportions of Fe2O3 and MnO2 were introduced into cobalt blue based on Co-Al spinel. The effect on the color of synthetic Kangxi blue and white pigment was discussed. The samples were tested and analyzed by XRD, energy spectrometer and colorimeter. The results showed that with the increase of Fe/Co value. The color of blue and white gradually changed from bright blue to dark blue. With the increase of Mn/Co value, the color of blue and blue gradually changed from bright blue to gray blue, and different proportion of CoAl2O4FeAl2O4 and MnAl2O4 were obtained in the process of synthesis. Mn0.83Al1.96Fe0.21O4 crystals, which interact with compounds formed by free iron, cobalt and manganese ions, affect the coloring effect of blue and white pigment.
【作者单位】：景德镇陶瓷学院;
【基金】：国家自然科学基金(51362016) 新世纪优秀人才支持计划资助省教育厅人文社科青年项目(LS1308)
【分类号】：J527
【正文快照】： 0引言青花瓷是中国陶瓷发展史上影响最大、成就最高的陶瓷品种之一,素有“国瓷”的美誉。据现有的考古资料表明[1],我国青花瓷的起源最早可以追溯到唐代;到元代,青花瓷逐渐发展成熟,至元代晚期,更呈现蓬勃发展之势;明清两代,青花瓷取代了青瓷、青白瓷和白瓷,一跃而成为中国陶

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