安徽繁昌柯家冲窑青白瓷釉化学组成及其制釉工艺来源研究

发布时间：2018-05-14 15:44

本文选题：繁昌窑 + 青白釉　；参考：《光谱学与光谱分析》2017年04期

【摘要】：为了解繁昌柯家冲窑青白瓷釉化学组成特征及其演变过程,并探索我国南方早期青白釉的工艺技术来源,本文运用能量色散X射线荧光光谱法(EDXRF)分析了柯家冲窑五代至北宋中期不同阶段青白瓷釉的化学组成,并将分析结果与同时期北方定窑白瓷釉及南方越窑青瓷釉化学组成进行了综合对比研究。结果显示,繁昌柯家冲窑青白釉化学组成在北宋中期时发生了明显变化,其中尤以SiO_2含量的下降和CaO含量的上升最为明显,着色元素Fe,Mn,Ti的氧化物含量自五代时期至北宋中期变化幅度很小,繁昌柯家冲窑青白釉釉色由偏白向偏青转变的原因可能与该窑瓷器胎色的不断加深有关。此外,主成分分析及具有相似功能特性的元素组合对比分析结果显示,繁昌柯家冲窑青白瓷釉的化学组成与北方定窑白瓷釉较为接近,其釉料配方工艺可能来源于同时期我国北方地区以定窑为代表的白瓷窑场。本文研究结果对了解我国早期青白瓷釉的化学组成特征及晚唐五代时期南、北方制瓷工艺技术交流问题等有重要学术价值。
[Abstract]:In order to understand the chemical composition and evolution process of white glaze in Fanchang Kejiachong Kiln, and to explore the technological source of the early green and white glaze in southern China, In this paper, the chemical composition of white glaze in different periods from five dynasties to the middle of Northern Song Dynasty was analyzed by energy dispersive X-ray fluorescence spectrometry (EDXRF). The chemical composition of the white glaze of Dingyao in the north and the blue glaze of the Yue kiln in the south were compared and studied comprehensively. The results showed that the chemical composition of green white glaze in Fanchang Kejiachong kiln changed obviously in the middle of Northern Song Dynasty, especially the decrease of SiO_2 content and the increase of CaO content. The oxide content of the coloring element Fe _ (mn) mn _ (Ti) changed very little from the five dynasties to the middle of Northern Song Dynasty. The reason for the change of glaze color from white to green in Fanchang Kejiachong Kiln may be related to the deepening of the color of the porcelain. In addition, the results of principal component analysis and comparative analysis of element combinations with similar functional characteristics show that the chemical composition of the white glaze of Fanchang Kejiachong kiln is close to that of the white porcelain glaze of the northern Dingyao kiln. The glaze formulation process may come from the white porcelain kiln in the northern part of China at the same time. The results of this study are of great academic value in understanding the chemical composition characteristics of China's early celadon glaze and the technical exchange between the south and the north of the late Tang and five dynasties.
【作者单位】：中国科学技术大学科技史与科技考古系;繁昌县文物管理局;
【基金】：教育部第48批留学回国人员科研启动基金繁昌县繁昌窑文化公园建设指挥部项目资助
【分类号】：K876.3

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